Statistical analyses of Global U-Pb Database 2017

The method of obtaining zircon samples affects estimation of the global U-Pb age distribution.Researchers typically collect zircons via convenience sampling and cluster sampling.When using these techniques,weight adjustments proportional to the areas of the sampled regions improve upon unweighted estimates.Here,grid-area and modern sediment methods are used to weight the samples from a new database of 418,967 U-Pb ages.Preliminary tests involve two age models.Model-1 uses the most precise U-Pb ages as the best ages.Model-2 uses the~(206)Pb/~(238)U age as the best age if it is less than a1000 Ma cutoff,otherwise it uses the~(207)Pb/~(206)Pb age as the best age.A correlation analysis between the Model-1 and Model-2 ages indicates nearly identical distributions for both models.However,after applying acceptance criteria to include only the most precise analyses with minimal discordance,a histogram of the rejected samples shows excessive rejection of the Model-2 analyses around the1000 Ma cutoff point.Because of the excessive rejection rate for Model-2,we select Model-1 as the preferred model.After eliminating all rejected samples,the remaining analyses use only Model-1 ages for five rock-type subsets of the database:igneous,meta-igneous,sedimentary,meta-sedimentary,and modern sediments.Next,time-series plots,cross-correlation analyses,and spectral analyses determine the degree of alignment among the time-series and their periodicity.For all rock types,the U-Pb age distributions are similar for ages older than 500 Ma,but align poorly for ages younger than 500 Ma.The similarities(500 Ma)and differences(500 Ma)highlight how reductionism from a detailed database enhances understanding of time-dependent sequences,such as erosion,detrital transport mechanisms,lithification,and metamorphism.Time-series analyses and spectral analyses of the age distributions predominantly indicate a synchronous period-tripling sequence of~91-Myr,~273-Myr,and~819-Myr among the various rock types.     

Late Holocene vertical land motion and relative sea‐level changes: lessons from the British Isles

Vertical land motion caused by continuing glacial isostatic adjustment is one of several important components of sea‐level change and is not limited just to previously glaciated regions. A national‐scale analysis for the British Isles shows an ellipse of present‐day relative uplift (relative sea‐level fall), ～1.2 mm a^?1, broadly centred on the deglaciated mountains of Scotland. The pattern of three foci of relative subsidence, ～1 mm a^?1, results from the additional interactions of the deglacial meltwater load on the Atlantic basin and the continental shelf, and the signal due to far‐field ice sheets. At a local scale, sediment compaction can more than double the rate of relative land subsidence. Relative land‐level change (the negative of relative sea‐level change) is not the same as vertical land motion. There is a spatial pattern in the difference between relative land‐level change and vertical land motion, with differences at present of approximately ?0.1 to ?0.3 mm a^?1 around the British Isles and +2.5 to ?1.5 mm a^?1 globally. For the wider scientific and user community, whether or not the differences are considered significant will depend upon the location, time frame and spatial scale of the study that uses such information. Copyright © 2011 John Wiley & Sons, Ltd.     

Marine protected areas—substantiating their worth

With the UK Marine Bill promoting the creation of a network of marine protected areas and similar commitments in other countries there is a need for tools to assist in their design and management. Although physical science often drives designation, the implementation of marine protected areas also encompasses political and socio-economic issues. This paper focuses on one tool in the armoury of decision-makers: choice experiments. It illustrates its application to the quantification of aspects of socio-economic value not readily incorporated into the evaluation of the costs and benefits of marine protected areas utilising cold-water deep coral reefs off the Republic of Ireland.     

Accretionary rims on inclusions in the Allende meteorite

Many inclusions in Allende, particularly those with irregular shapes, are surrounded by a sequence of thin layers which differ from one another in texture, mineralogy and mineral-chemistry. The layer underlying all others contains either: IA, pyroxene needles + olivine + clumps of hedenbergite and andradite; IB, olivine doughnuts; or IC, rectangular olivine crystals. The next layer outward, II, contains tiny (<5 μm) olivine plates and Layer III large (5–10 μm) olivine laths. The final layer, IV, occurs as clumps of andradite + hedenbergite surrounded by magnesium-rich pyroxene needles. It separates Layer III from the Allende matrix which is more poorly sorted and more sulfide-rich than Layer III. Nepheline and iron sulfide are common constituents of most layers, the latter being particularly fine-grained and abundant in Layer II. Although not every layer is present on every inclusion, the sequence of layers is constant. Evidence that the rims are accretionary aggregates includes the presence of highly disequilibrium mineral assemblages and the fact that they are highly porous masses consisting of many euhedral crystals with few intergrowths. In addition, the layers are thickest in topographic hollows on the surfaces of inclusions and the inner layers are absent or discontinuous beyond such irregularities, suggesting that the probability of accretion of crystals was low initially, except in pockets, and became greater later, after a soft cushion of accreted condensate crystals had already formed. Separation of assemblages of different mineralogy, mineral-chemistry and texture into different rim layers seems best explained by nebular models in which long, slow cooling histories allow differentiation during condensation by grain/gas separation processes.     

A high stand of the Dead Sea at the end of the Neolithic period: Paleoclimatic and archeological implications

A salt deposit, covering land snail shells and rocks, was found in a space under a large boulder at Qumran near the Dead Sea at -280 m elevation and marks the level of the Dead Sea at c. 6700 yr BP. This level is some 120 m above the modern Dead Sea level and thus indicates substantially higher rainfall than at present. Archeological evidence indicates a falling sea level immediately following this time. Despite the favorable climate at the time of the high stand, the presently more arid areas of the southern Levant were nearly deserted. Only during the subsequent period of aridification did these areas become extensively settled by people of the Chalcolithic culture.     

Carbon and oxygen isotope composition of shell carbonate of desert land snails

Variation in¹³C/¹²C and¹⁸O/¹⁶O ratios in the shell carbonate of several species of land snails was studied along a climatic gradient in semi-arid to arid areas in the southern Levant.¹³C was found to be enriched in snails from communities having plants with a C₄ photosynthetic pathway. Depleted δ¹³C values were found in areas with high mean annual rainfall, apparently due to higher input of metabolic CO₂ as a result of greater snail activity. Shell carbonate δ¹⁸O values show a weak relation to the δ¹⁸O values of rainwater. The shell δ¹⁸O values are enriched by 2–8‰ relative to isotopic equilibrium with environmental waters. Enrichment is suggested to result from metabolic effects on body water (with lower activity producing greater enrichment) but evaporation could also be a factor. Consistent differences in both¹³C and¹⁸O were found among species and may relate to the time when shell deposition occurs. As with most paleoenvironmental indicators, the application of shell isotopes is complicated by the multiplicity of controls of isotopic composition.     

Refractory inclusions in the Murchison meteorite

Mineralogical and petrographic studies of a wide variety of refractory objects from the Murchison C2 chondrite have revealed for the first time melilite-rich and feldspathoid-bearing inclusions in this meteorite, but none of these is identical to any inclusion yet found in Allende. Blue spinel-hibonite spherules have textures indicating that they were once molten, and thus their SiO₂-poor bulk composition requires that they were exposed to higher temperatures (>1550°C) than those deduced so far from any Allende inclusion. Melilite-rich inclusions are similar to Allende compact Type A's, but are more Al-, Ti-rich. One inclusion (MUCH-1) consists of a delicate radial aggregate of hibonite crystals surrounded by alteration products, and probably originated by direct condensation of hibonite from the solar nebular vapor. The sinuous, nodular and layered structures of another group of inclusions, spinel-pyroxene aggregates, suggest that these also originated by direct condensation from the solar nebular gas. Each type of inclusion is characterized by a different suite of alteration products and/or rim layers from all the other types, indicating modification of the inclusions in a wide range of different physico-chemical environments after their primary crystallization. All of these inclusions contain some iron-free rim phases. These could not have formed by reaction of the inclusions with fluids in the Murchison parent body because the latter would presumably have been very rich in oxidized iron. Other rim phases and alteration products could have formed at relatively low temperatures in the parent body, but some inclusions were not in the locations in which they were discovered when this took place. Some of these inclusions are too fragile to have been transported from one region to another in the parent body, indicating that low temperature alteration of these may have occurred in the solar nebula.     

Luminescence-dating zeroing tests in Lake Hoare, Taylor Valley, Antarctica

In two of the perennially ice-covered lakes in the McMurdo Dry Valleys, lakes Hoare and Bonney in the Taylor Valley, bottom water has ¹⁴C ages of 2.7 ka and 10 ka (respectively), rendering ¹⁴C ages of bottom sediments highly problematic. Consequently, we tested the effectiveness of thermoluminescence (TL) zeroing in polymineral fine silt material from several depositional environments around and on the lake (stream suspensions, ice-surface sand dune, and silty sand from near the top of the more-than-3m-thick ice). We also conducted TL and infrared-stimulated-luminescence (IRSL) dating tests on material from three box cores recovered from the bottom of Lake Hoare, in a transect away from the abutting Canada Glacier. We observed effective zeroing of light-sensitive TL in suspended silt from one input stream and less effective zeroing from another stream. We observed effective zeroing of light-sensitive TL also in silt from a glacier-proximal eolian ice-surface dune and from sand from within the upper 5 cm of ice. In contrast, in box-core 1, the bottom sediment yielded minimum TL apparent ages of 1500-2600 yrs, with no discernable stratigraphic depth trend. IRSL dating applied to the same box-core samples produced significantly lower age estimates, ranging from ~600 ± 200 yrs to 1440 ± 270 yrs top-to-bottom, an improvement over the depth-constant ~2200 yrs TL ages. In two other cores closer to the Canada Glacier, IRSL ages from ~600 ± 200 yrs (top) to ~ 2900± 300 yrs (at depth) were measured. Not only are the IRSL ages a significant improvement over the TL results, but the near-core-top IRSL ages are also a dramatic improvement over the ¹⁴C results (~2.7 ka). IRSL dating has a demonstrated potential to supplant ¹⁴C dating for such antarctic lacustrine deposits.